redump.org provides metadata for most of the PSP discs, but of course don't host any downloads.
I didn't actually know that redump.org had a PSP database because it's not visible from the main website's list of platforms, but it's really there:
http://redump.org/discs/system/psp
So if we can get our hands on the actual database, or find an easy way to query it, it should be easy to add a way to check that an ISO has not been modified from its original form.